Bifunctional Polymeric Organocatalysts and Their Application in the Cooperative Catalysis of Morita–Baylis–Hillman Reactions

CKW Kwong, R Huang, M Zhang…

文献索引：Kwong, Cathy Kar-Wing; Huang, Rui; Zhang, Minjuan; Shi, Min; Toy, Patrick H. Chemistry - A European Journal, 2007 , vol. 13, # 8 p. 2369 - 2376

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被引用次数: 77

摘要

Abstract A series of soluble, non-cross-linked polystyrene-supported triphenylphosphane and 4-dimethylaminopyridine reagents were prepared. Some of these polymeric reagents contained either alkyl alcohol or phenol groups on the polymer backbone. The use of these materials as organocatalysts in a range of Morita–Baylis–Hillman reactions indicated that hydroxyl groups could participate in the reactions and accelerate product formation. In the ...