Catalysis Communications

Epoxidation of olefins with O 2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material

A Zhang, L Li, J Li, Y Zhang, S Gao

文献索引：Zhang, Aiping; Li, Linqing; Li, Jun; Zhang, Yi; Gao, Shuang Catalysis Communications, 2011 , vol. 12, # 13 p. 1183 - 1187

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被引用次数: 27

摘要

Abstract Co-containing zeolitic imidazolate framework material (Co-ZIF) was prepared and its catalytic performance in the aerobic epoxidation of olefins using isobutyraldehyde as reductant under mild conditions was first studied. Co-ZIF was characterized by XRD, FT-IR and X-ray single-crystal diffraction. It showed good performance in the epoxidation of olefins, with 100% conversion, 98.5% selectivity and 638.3 turnover frequency for the epoxidation ...