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Quantitative contrasts in the copolymerization of acrylate-and methacrylate-based comonomers

…, P Enohnyaket, MF Drenski, R Shunmugam…

文献索引:Alb, Alina M.; Enohnyaket, Pascal; Drenski, Michael F.; Shunmugam, Raja; Tew, Gregory N.; Reed, Wayne F. Macromolecules, 2006 , vol. 39, # 24 p. 8283 - 8292

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被引用次数: 23

摘要

Automatic continuous online monitoring of polymerization reactions (ACOMP) was used to assess quantitatively the reactivity, average composition drift and distributions, as well as molar mass and intrinsic viscosity evolution of comonomers from the acrylate and methacrylate families during free radical copolymerization. In the latter case, N- methacryloxysuccinimide (MASI) was of chief interest because of its promise as a starting ...