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Tetrahedron Letters

Oxidation using distannoxane II. Selective and mild oxidation of sulphides

Y Ueno, T Inoue, M Okawara

文献索引:Ueno,Y. et al. Tetrahedron Letters, 1977 , # 28 p. 2413 - 2416

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被引用次数: 15

摘要

2 In such natural product synthesis, however, we have encountered the difficulty for the sodium periodate oxidation of certain sulphides which have hydrophobic long alkyl chain, apparently because such hydrophobic sulphides are scarcely miscible with aqueous organic solvents. While the hydrogen peroxide or peracid oxidation of sulphides require the special care to avoid the over-oxidation to sulphones or possible side reactions such as ...