Enantioselective epoxidation of unfunctionalized simple olefins by non-racemic molybdenum (VI)(oxo-diperoxo) complexes

…, U Leyrer, C Mark, P Pitchen, HB Kagan

文献索引：Schurig, V.; Hintzer, K.; Leyrer, U.; Mark, C.; Pitchen, P.; Kagan, H. B. Journal of Organometallic Chemistry, 1989 , vol. 370, p. 81 - 96

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被引用次数: 51

摘要

Abstract Molybdenum (VI)(oxo-diperoxo) complexes bearing bidentate ligands with hydroxy and carbonyl functions show asymmetric induction in the stoichiometric epoxidation of simple prochiral olefins. The influence of the ligand and alkene structure on the enantiomeric excess of the oxiranes has been investigated. The addition of chiral diols to the molybdenum (VI)(oxo-diperoxo) reagents gives high enantiomeric excesses probably ...