Sulphonyl-stabilised sulphonium ylids

P Robson, PRH Speakman, DG Stewart

文献索引：Robson,P. et al. Journal of the Chemical Society [Section] C: Organic, 1968 , p. 2180 - 2183

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被引用次数: 8

摘要

1-Dodecylmethylsulphonium methylsulphonylmethylid and dimethylsulphonium 1- dodecylsulphonyl methylid have been prepared. The ylids are stable crystalline solids but undergo rearrangements in solution at elevated temperatures and under the influence of ultraviolet light. Sulphonyl carbenes are not generated during t