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The disarming effect of the 4, 6-acetal group on glycoside reactivity: torsional or electronic?

HH Jensen, LU Nordstrøm, M Bols

文献索引:Journal of the American Chemical Society, , vol. 126, # 30 p. 9205 - 9213

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被引用次数: 174

摘要

... Journal of the ... 2004, 126 (30), pp 9205–9213. DOI: 10.1021/ja047578j. Publication Date (Web): July 10, 2004. Copyright © 2004 American Chemical Society. ... The dinitrophenyl glycosides allow us to determine first-order rate constants for spontaneous hydrolysis by the method of ...