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The C4-Saccharinic Acids. VIII. Some Reactions of Pentaerythritol. Preparation of 2, 2'-Diiodoisobutyric Acid and its Hydrolysis to 2, 2'-Dihydroxyisobutyric Acid1

JWE Glattfeld, JM Schneider

文献索引:Glattfeld; Schneider Journal of the American Chemical Society, 1938 , vol. 60, p. 418

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被引用次数: 5

摘要

Summary Evidence is submitted which leads to the conclusion that the hydroxyl group in &cholesterol is in position six of the sterol molecule and that during its formation from cholesteryl p-toluenesulfonate a molecular rearrangement occurs. The results obtained and described in this paper substantiate the validity of the structural formula proposed by investigators in this Laboratory for i-cholesterolaj6 and for the isomeric ethers of ...