Journal of Molecular Liquids

Studies on the kinetics of tripropylammonium fluorochromate oxidation of some aromatic alcohols in non-aqueous media

SS Mansoor, SS Shafi

文献索引：Mansoor, S. Sheik; Shafi, S. Syed Journal of Molecular Liquids, 2010 , vol. 155, # 2-3 p. 85 - 90

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被引用次数: 22

摘要

The oxidation of benzyl alcohol (BnOH) and a few para-substituted benzyl alcohols by tripropylammonium fluorochromate (TriPAFC) in dimethylsulphoxide (DMSO) leads to the formation of corresponding aldehydes. The reaction is first order each in TriPAFC and the alcohols. The reaction is catalysed by hydrogen ions. The hydrogen ion dependence has the form: kobs= a+ b [H+]. The oxidation of α α′-dideuterio benzyl alcohol exhibited a ...