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Oxone oxidation of selenides: a mild and efficient method for the preparation of selenones

P Ceccherelli, M Curini, F Epifano…

文献索引:Ceccherelli, Paolo; Curini, Massimo; Epifano, Francesco; Marcotullio, Maria Carla; Rosati, Ornelio Journal of Organic Chemistry, 1995 , vol. 60, # 26 p. 8412 - 8413

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被引用次数: 39

摘要

Most investigations have focused on the preparation and reactivity of selenoxides,'but selenones have received little attention. Selenones have been prepared by oxidation of selenides using an excess of peroxycarboxylic acids, 2 potassium permanganate, 2 or hydrogen peroxide in the presence of seleninic acid. 3 These methods have several disadvantages and can be applied only to selenides with limited structural features in the ...