Keywords: Palladium / Primary benzylamines / NMR spectroscopy / Structure elucidation / Conformation analysis ... The structure of dimer 1a thus formed and the palladacycle conformation were established on the basis of 1H-NMR ... Despite numerous publications dealing with the direct ... Widening the scope of direct intramolecular palladation ... The pioneer work of Lewis and co-workers[14] cannot be ... Our investigation of the direct ortho-palladation of sec-