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Journal of the American Chemical Society

STEREOCHEMISTRY OF DIPHENYL. XXI. RESOLUTION OF 2, 4, 6, 2', 4', 6'-HEXACHLORO-3, 3'-DICARBOXYDIPHENYL1, 2

J White, R Adams

文献索引:White; Adams Journal of the American Chemical Society, 1932 , vol. 54, p. 2104,2107

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被引用次数: 7

摘要

Another example of this type is described in this communication in which the chlorine atom is present in the positions adjacent to the diphenyl linkage, The substance prepared was 2, 4, 6, 2', 4', 6 '-hexachloro-3, 3 '-di-carboxydiphenyl (IV). It was resolved through the brucine salt. The d-active compound was stable to racemization in boiling alcohol, glacial acetic acid and, as the sodium salt, in boiling water. The compound was synthesized by starting with ...