Journal of solution chemistry

Kinetics of hydrolysis of some new heterocyclic azomethines

MR Mahmoud, MMA Hamed, AM Shaker

文献索引：Mahmoud, Mohamed Rafat; Hamed, Maher Mohamed Ahmed; Shaker, Ali Mohamed Journal of Solution Chemistry, 1986 , vol. 15, # 9 p. 765 - 776

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被引用次数: 19

摘要

Abstract Kinetics of base hydrolysis of new heterocyclic azomethines derived from active methyl quaternary salts and aromatic nitroso compounds were investigated in the presence of 70%(wt/wt) water-methanol. The base hydrolysis of these compounds is strictly first-order with respect to OH− and azomethine. The rate determining step is suggested to be the attack of the hydroxide ion on the free base. Effects of water content and nature of organic ...