Preparation and helium (He I) photoelectron spectra of the halogen thiocyanates, XSCN (X= chlorine and bromine)

DC Frost, CB MacDonald, CA McDowell…

文献索引：Frost, D.C.; MacDonald, C.B.; McDowell, C.A.; Westwood, N.R.C. Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4423 - 4427

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被引用次数: 30

摘要

Abstract: The unstable chlorine and bromine thiocyanate molecules have been generated in the gas phase by reaction of AgSCN (solid) or (SCN) z (gas) with molecular chlorine or bromine, respectively. ISCN does not appear to be formed by this route. The structures are established as nonlinear XSC= N molecules, and the observed He1 photoelectron spectra are assigned on this basis with the assistance of minimal basis ab initio calculations. The ...