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Changes in Configuration of Some Nickel (II) Complexes1

F Basolo, WR Matoush

文献索引:Basolo, F.; Mathoush, W. R. Journal of the American Chemical Society, 1953 , vol. 75, p. 5663 - 5666

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被引用次数: 56

摘要

Diamagnetic nickel (I1) complexes were allowed to react with anhydrous pyridine. In several instances it was possible to isolate well-defined crystalline compounds of hexacoordinated nickel (11) containing two molecules of pyridine. These solid compounds were paramagnetic and removal of pyridine at reduced pressures yielded the original diamagnetic materials. It is therefore concluded that the paramagnetism of certain pyridine ...