Substituted Phenylsilanes. I. The Autoxidation of o-, m-and p-Trimethylsilylethylbenzene1

RG Severson, RJ Rosscup

文献索引：Severson; Rosscup Journal of the American Chemical Society, 1954 , vol. 76, p. 4552

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被引用次数: 12

摘要

The trimethylsilylethylbenzenes have been prepared and the oxidation of these silanes with oxygen has been studied Thk oxidation, carried out at 200-220" in the presence of chromic oxide and calcium carbonate, has given moderate yields of 0-, m-and p- trimethylsilylacetophenone as well as the corresponding trimethylsilylbenzoic acids. The resulting new organosilanes have been characterized and derivatives have been ...