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Vinyl Sulfides. IV. Ketene Mercaptals

HJ SCHNEIDER, JJ Bagnell…

文献索引:Schneider,H.J. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 1987 - 1990

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被引用次数: 15

摘要

Ketene mercaptals, of the general formula CHFC (SR)~, have been relatively unknown. Rothstein'has reported the preparation of methyl ketene diethyl mercaptal by the abnormal dehydrohalogenation of p-chloropropionaldehyde diethyl mercaptal. This proposed ketene dimercaptal structure has since been questioned by Parham.* Ketene dimethyl mercapt, al has been disclosed3 as a pyrolysis product in a patent concerned with sulfur-containing ...