Chemical Communications

Triple C–H activation of 1, 5-bis (di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex

VF Kuznetsov, AJ Lough, DG Gusev

文献索引：Kuznetsov, Vladimir F.; Lough, Alan J.; Gusev, Dmitry G. Chemical Communications, 2002 , # 20 p. 2432 - 2433

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被引用次数: 17

摘要

This communication reports the preparation of a novel trans-chelating diphosphine, 1, 5-bis (di-tert-butylphosphino)-2-(S)-dimethylaminopentane, that undergoes triple C–H activation in reaction with [RuCl2 (p-cymene)] 2 to give a chiral square-pyramidal 16-electron carbene complex of ruthenium.