The Journal of Organic Chemistry

1, 4-Dimethyl-1, 4-dihydro-1, 2, 4, 5-tetrazine and its N-alkyl salt. Synthesis, structure, and chemistry

H Kohn, RA Olofson

文献索引：Kohn,H.; Olofson,R.A. Journal of Organic Chemistry, 1972 , vol. 37, # 22 p. 3504 - 3509

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被引用次数: 8

摘要

1, 4-Dimethyl-1, 4-dihydro-l, 2, 4, 5-tetrazine (1) has been prepared by a convenient two- step route and shown to rearrange to a triazoline (11) in base. Attempts to differentiate between the several possible planar and boat conformations for the &-available electron system (1) by nmr failed, but data pertinent to this problem were obtained from studies of the mechanism of the process, 1-P 11, and of the alkylation of 1, which occurs at nitrogen ...