Selective telomerization of butadiene with various nucleophiles catalyzed by polymer-bound palladium (0) complexes

…, M Terasawa, T Imanaka, S Teranishi

文献索引：Kaneda, Kiyotomi; Kurosaki, Hiroo; Terasawa, Masami; Imanaka, Toshinobu; Teranishi, Shiichiro Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2356 - 2362

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被引用次数: 62

摘要

The telomerization of butadiene with various nucleophiles such as alcohols, amines, carboxylic acids, phenol, water, and silane was carried out by using the phosphinated polystyrene-bound palladium (0) catalysts. In secondary amine reactions, 2: 1 adducts of butadiene and amines are selectively formed, and the reactivities decrease with an increase in the steric bulk about nitrogen of the amines: morpholine> piperidine> diethylamine> ...