Theoretical study of the experimental coordination behavior of N-(2-aminophenyl)-d-glycero-d-gulo-heptonamide to Hg (II) ion

MI Bernal-Uruchurtu, AJ Metta-Magaña…

文献索引：Bernal-Uruchurtu, Margarita I.; Metta-Magana, Alejandro J.; Guerrero-Alvarez, Jorge A.; Reyes-Martinez, Reyna; Tlahuext, Hugo Carbohydrate Research, 2008 , vol. 343, # 16 p. 2804 - 2812

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被引用次数: 1

摘要

The reactivity of N-(2-aminophenyl)-d-glycero-d-gulo-heptonamide (adgha), with the group 12 cations, Zn (II), Cd (II), and Hg (II), was studied in DMSO-d6 solution. The studied system showed a selective coordination to Hg (II), and the products formed were characterized by 1H and 13C NMR in DMSO-d6 solution and fast atom bombardment (FAB+) mass spectra. The expected coordination compounds,[Hg (adgha)](NO3) 2 and [Hg (adgha) 2](NO3) 2, ...