Synthesis and characterization of perhalophenyltin derivatives. Study of their reactivity toward phosphine gold (I) chlorides

RV Bojan, JM López-de-Luzuriaga, M Monge…

文献索引：Bojan, R. Vilma; Lopez-De-Luzuriaga, Jose M.; Monge, Miguel; Olmos, M. Elena Journal of Organometallic Chemistry, 2010 , vol. 695, # 22 p. 2385 - 2393

全文：HTML全文

被引用次数: 6

摘要

The (perhalophenyl) tin derivatives [SnR4](1–3) and [SnR3Cl](4–6)(R= C6F5, C6F3Cl2, C6Cl5) were prepared from SnCl4 and LiR or [SnR4] in the appropriate molar ratio, while the dinuclear complexes [SnR3] 2 (7–9) were obtained by treatment of [SnR3Cl] with potassium under toluene reflux. Complexes 2, 6· 0.5 toluene and 7 were structurally characterized, the latter displaying a Sn–Sn bond of 2.808 (7) Å, which indicates a strong ...