Bulletin of the Chemical Society of Japan

The Acid-catalyzed Reaction of Cycloalkanones with Formaldehyde

F Hirano, S Wakabayashi

文献索引：Hirano,F.; Wakabayashi,S. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 2579 - 2583

被引用次数: 19

摘要

The acid-catalyzed reactions of several cycloalkanones, such as cyclopentanone (1a), 2- methylcyclopentanone (1b), cyclohexanone (1c), 2-methylcyclohexanone (1d), and 2- isopropyl-5-methylcyclohexanone (1e), with formaldehyde were investigated. These reactions involved an aldol condensation analogous to the Prins reaction, and they afforded methylol derivatives and cyclic ethers. It was found that the formation of the products is ...

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