Kinetics and Mechanism of Oxidation of Ethyl Phenylthioacetates by Bromamine-B.

…, KI Sathiyanarayanan, M Gopalakrishnan

文献索引：Gurumurthy, Rajagopal; Sathiyanarayanan, Kulathu Iyer; Gopalakrishnan, Mannathusamy Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 4 p. 1096 - 1100

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被引用次数: 17

摘要

The kinetics of oxidation of several substituted ethyl phenylthioacetates by bromamine-B (sodium salt of N-bromobenzenesulfonamide) has been studied in 50%(v/v) aqueous ethanol medium. Disodium hydrogenphosphate and sodium dihydrogenphosphate buffer has been used. The reaction is of a total second order, first order each with respect to the reactants. A catalytic effect of mercury has been observed and the order with respect to Hg ...