Carbanions as intermediates in the formation of Grignard reagents

…, G Schat, OS Akkerman, F Bickelhaupt, AL Spek

文献索引：Van Klink, Gerard P.M.; De Boer, Henricus J.R.; Schat, Gerrit; Akkerman, Otto S.; Bickelhaupt, Friedrich; Spek, Anthony L. Organometallics, 2002 , vol. 21, # 10 p. 2119 - 2135

全文：HTML全文

被引用次数: 50

摘要

The observation of inter-and/or intramolecular migrations of organotin and organosilicon groups during the Grignard reagent formation reaction is explained by the occurrence of reactive carbanion intermediates. While radicals are important intermediates, too, they are shown not to be responsible for these arrangements.