Tetrahedron letters

Design of a highly efficient catalyst for the oxaziridinium-mediated epoxidation of olefins by Oxone®

L Bohé, M Kammoun

文献索引：Bohe, Luis; Kammoun, Majed Tetrahedron Letters, 2004 , vol. 45, # 4 p. 747 - 751

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被引用次数: 36

摘要

The potential of oxaziridinium salts as electrophilic-oxygen transfer reagents has emerged clearly since the pioneering reports on oxaziridinium chemistry by X. Lusinchi and co-workers. 1 Some time later, this group described the oxidation of thioethers, 2 amines and imines 3 and established that oxaziridinium salts epoxidize the carbon–carbon double bonds of simple olefins. 4 They also showed that nonracemic oxaziridiniums are suitable reagents for the asymmetric ...