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Piperidine Derivatives. XX. The Preparation and Reactions of 1-Methyl-3-piperidone

SM McElvain, JF Vozza

文献索引:McElvain; Vozza Journal of the American Chemical Society, 1949 , vol. 71, p. 896,898

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被引用次数: 28

摘要

The recent report'on the reactions of l-methyl-4-piperidone, particularly those with a variety of aromatic aldehydes, indicated a study of similar reactions with the unsymmetrical isomer, 1-methyl-3-piperidone (VI). The preparation of this latter compound from 1-methyl-4- carbethoxy-3-piperidone (V), obtained by the cyclization of the diester (IV) was reported earlier2 from this Laboratory. It seemed of special interest to determine the reactivity of VI ...