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1, 3-Dipolar addition of an oxazolium 5-oxide to cyclopentadienequinone and the anthracenequinone

JA Myers, WW Wilkerson…

文献索引:Myers,J.A. et al. Journal of Organic Chemistry, 1975 , vol. 40, p. 2875 - 2877

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被引用次数: 7

摘要

Reaction of 3-methyl-2, 4-diphenyloxazolium 5-oxide (1) with cyclopentadienequinone and anthracenequinone, respectively, gave 1: l adducts 2 and 3 in which the elements of carbon dioxide have been retained. The N-bridged lactone structures assigned to 2 and 3 are based on the spectral analyses and chemical decompositions. Conversions of 2 and 3 into the corresponding pyrrolines 4 and 5 and pyrroles 6 and 7 are described. Formation of a ...