Microwave rotational spectrum, electric dipole moment and geometry of 2-bicyclo [3.1. 0] hexanone

AP Davies, AC Legon, DJ Millen, AJ Roberts

文献索引：Davies, Ann P.; Legon, A. C.; Millen, D. J.; Roberts, A. J. Journal of Molecular Structure, 1984 , vol. 112, p. 9 - 18

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摘要

Abstract We report the microwave rotational spectrum of 2d̄bicyclo [3.1. 0] hexanone in its vibrational ground state and in vibrationally excited states associated with the bending mode ν B of the five-membered ring. Variation of the rotational constants with ν B allows the conclusion that the five-membered ring is effectively planar although the mode v B is governed by an asymmetric potential energy function. Measurement of teh Stark effect in a ...