Application of copper (I) halides to modifying reactivity of polyhalomethanes and arenesulfonyl chlorides in free-radical addition.“Cross-halogenation” reaction

AS Dneprovskii, AN Kasatochkin, VP Boyarskii…

文献索引：Dneprovskii; Kasatochkin; Boyarskii; Ermoshkin; Yakovlev Russian Journal of Organic Chemistry, 2006 , vol. 42, # 8 p. 1120 - 1130

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被引用次数: 9

摘要

Abstract In the free-radical addition of a number of organohalogen reagents to cyclic alkenes and dienes in the presence of copper (I) halides the composition of the reaction products is governed by the stage of a fast halogen transfer from the copper derivative to the alkyl radical. Under these conditions in contrast to the free-radical addition reactions initiated by UV light or peroxide initiators the intramolecular rearrangements are suppressed, the ...