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Australian journal of chemistry

Dihydro-1, 2, 4-triazin-6 (1H)-ones. II Synthesis of Several Methylated 3-Phenyl-4, 5-dihydro-1, 2, 4-triazin-6 (1H)-ones

DJ Collins, TC Hughes, WM Johnson

文献索引:Collins, David J.; Hughes, Timothy C.; Johnson, Wynona M. Australian Journal of Chemistry, 1999 , vol. 52, # 5 p. 379 - 385

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被引用次数: 6

摘要

Abstract Novel syntheses of 4, 5-dihydro-1, 2, 4-triazin-6 (1H)-ones were developed by use of imidoyl chlorides. The overall yield of 4, 5-dihydro-1, 2, 4-triazin-6 (1H)-ones prepared from amino acid imidates and hydrazines was improved by the development of a much more efficient synthesis of the imidates. The new 1, 2-, 1, 4-and 5, 5-dimethyl dihydro-1, 2, 4-triazin- 6 (1H)-ones have been synthesized by cyclocondensation/cycloaddition pathways. Base- ...