Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide

VR Akhmetova, GR Nadyrgulova, TV Tyumkina…

文献索引：Akhmetova; Nadyrgulova; Tyumkina; Starikova; Antipin; Kunakova; Dzhemilev Russian Journal of Organic Chemistry, 2007 , vol. 43, # 6 p. 918 - 925

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被引用次数: 16

摘要

Abstract Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3: 2: 1 give 47–73% of N-hydroxy (or hydroxyalkyl)-1, 3, 5-dithiazinanes. The reactions of CH 2 O with H 2 S and hydroxylamine or α-amino alcohols at a ratio of 4: 3: 1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH 2 O and H 2 S under ...