Journal of the Chemical Society C: Organic

Studies of organophosphorochloridates. Part II. Reactions of steroid phosphorodichloridates

RJW Cremlyn, NA Olsson

文献索引：Cremlyn,R.J.W.; Olsson,N.A. Journal of the Chemical Society [Section] C: Organic, 1971 , p. 2023 - 2027

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被引用次数: 4

摘要

The preparation of the following steroid phosphorodichloridates is described: cholestanyl, epicholestanyl, epicholesteryl, and the derivatives of methyl 3α-hydroxy-5β-chlolanate, and ergosta-8 (14) en-3β-ol. The formation of the phosphorodichloridates was followed by tlc Attempted phosphorylation of 3, 5-cyclocholestan-6β-ol, and 6β-hydroxycholest-4-en-3-ol gave cholesteryl phosphorodichloridate and cholestane 3, 6-dione respectively. The ...