Structural Diversity of Copper (I)–N??Heterocyclic Carbene Complexes; Ligand Tuning Facilitates Isolation of the First Structurally Characterised Copper (I)–NHC …
BRM Lake, CE Willans
文献索引：Lake, Benjamin R. M.; Willans, Charlotte E. Chemistry - A European Journal, 2013 , vol. 19, # 49 p. 16780 - 16790
Abstract The preparation of a series of imidazolium salts bearing N-allyl substituents, and a range of substituents on the second nitrogen atom that have varying electronic and steric properties, is reported. The ligands have been coordinated to a copper (I) centre and the resulting copper (I)–NHC (NHC= N-heterocyclic carbene) complexes have been thoroughly examined, both in solution and in the solid-state. The solid-state structures are highly ...
