The Journal of organic chemistry

Rational synthesis of meso-substituted porphyrins bearing one nitrogen heterocyclic group

D Gryko, JS Lindsey

文献索引：Gryko, Dorota; Lindsey, Jonathan S. Journal of Organic Chemistry, 2000 , vol. 65, # 7 p. 2249 - 2252

全文：HTML全文

被引用次数: 98

摘要

Tailoring the perimeter of the porphyrin macrocycle with diverse substituents in defined patterns is essential for studies in biomimetic and materials chemistry. 1, 2 Small nitrogen heterocycles are substituents of particular interest, 3 providing sites for metal coordination, hydrogenbonding, alkylation (water solubilization), and modulation of the electronic properties of the porphyrin. Indeed, pyridine substituents have yielded a broad array of ...