Thionyl??chloride??pyridine??mediated rearrangement of tertiary alcohols

AK Banerjee, W Vera

文献索引：Banerjee, Ajoy K.; Vera, William Recueil des Travaux Chimiques des Pays-Bas, 1995 , vol. 114, # 3 p. 87 - 90

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被引用次数: 7

摘要

Abstract Tertiary alcohols 5 and 8 undergo rearrangement on treatment with thionyl chloride and pyridine, yielding octahydronaphthalenes 6 and 9, respectively. Alcohol 12 under similar treatment affords a mixture of tetrahydronaphthalene 14 and diene 15, whereas alcohol 22 suffers no rearrangement but produces olefin 23.