Procedure for the Rapid Synthesis of the Monomer 1, 4-Bis (chloromethyl)-2-(2-ethylhexyloxy)-5-methoxybenzene

N Anderson, W Bagge, C Webber, P Zarras…

文献索引：Anderson, Nichole; Bagge, Whitney; Webber, Cindy; Zarras, Peter; Davis, Matthew C. Synthetic Communications, 2008 , vol. 38, # 22 p. 3903 - 3908

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被引用次数: 3

摘要

Abstract The alkylation of 4-methoxyphenol with 2-ethylhexyl bromide was accelerated by using potassium tert-butoxide in dimethylformamide. Subsequent chloromethylation occurred quickly using acetic acid as a cosolvent to give the poly [(2-(2-ethylhexyloxy)-5- methoxy-p-phenylene) vinylene](MEH-PPV) monomer in 61% overall yield on a 2-mol scale.