Tetrahedron Letters

Homoallylically controlled epoxidation of Δ 4-cis-1, 2-disubstituted cyclohexenes

DP Rotella

文献索引：Rotella, David P. Tetrahedron Letters, 1989 , vol. 30, # 15 p. 1913 - 1916

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被引用次数: 19

摘要

Abstract Stereochemical control during the epoxidation of cis-1-[N-Cbz]-2-[hydroxymethyl]- cyclohex-4-enes with MCPBA is dependent on hydroxyl functionalization which apparently determines ring conformation. Unprotected or acetate-derivatized compounds afford