The Substituent Effect. V. NMR Chemical Shifts of Hydrogen-bonding Hydroxyl Proton of Phenols in DMSO

M Fujio, M Mishima, Y Tsuno, Y Yukawa…

文献索引：Fujio,M. et al. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 2127 - 2133

全文：HTML全文

被引用次数: 29

摘要

The chemical shifts of the hydrogen bonded OH proton of m-and p-substituted phenols, and 4-substituted 2-cresols, 3-cresols, and 2, 6-xylenols were determined in DMSO. The effects of substituents on the hydroxyl chemical shift of these series were correlated linearly with each other (correlation coefficient> 0.999), except for the bulky planar substituents in the 3- cresol series which may be subject to the steric loss of their coplanarity with the benzene ...