Journal of the American Chemical Society

Ultraviolet absorption spectra of derivatives of polysilanes. A probe of (p. far. d). pi. bonding in organosilicon compounds

CG Pitt

文献索引：Pitt,C.G. Journal of the American Chemical Society, 1969 , vol. 91, p. 6613 - 6622

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被引用次数: 62

摘要

Abstract: The electronic absorption spectra of permethylated polysilanes, Me (SiMe&Me, are discussed, together with the possibility that the perturbation of the spectra by various substituents may provide an estimate of (p-+ d), bonding, The various possible assignments of the ground and excited states of the long-wavelength absorption band are considered in the light of ionization potential measurements, and the spectral properties of phenyl ...