Tetrahedron

Chemistry of trivalent iodine—III: The action of iodobenzene dichloride on primary alcohols and aldehydes11NCL Communication No. 2763.

TP Mohandas, AS Mamman, PM Nair

文献索引：Mohandas, T. P.; Mamman, Ajit, S.; Nair, P. Madhavan Tetrahedron, 1983 , vol. 39, # 7 p. 1187 - 1188

全文：HTML全文

被引用次数: 3

摘要

Iodobenzene dichloride reacts with saturated primary alcohols at room temperature in the presence of pyridine to give esters and acid chlorides. With the corresponding aldehydes, only the latter type of product is obtained. While pivaldehyde reacts normally, benzaldehyde is unaffected by the reagent under the same conditions. Presence of moisture results in formation of acids. It is suggested that reactions of both types of substrates involve base ...