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Regioselective Arylation and Alkynylation of 2, 3??Dibromo??1H??inden??1??one by Suzuki Miyaura and Sonogashira Cross??Coupling Reactions

…, N Eleya, H Feist, A Villinger, P Langer

文献索引:Khera, Rasheed Ahmad; Hussain, Munawar; Hung, Nguyen Thai; Eleya, Nadi; Feist, Holger; Villinger, Alexander; Langer, Peter Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 469 - 482

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被引用次数: 3

摘要

Abstract Suzuki [BOND] Miyaura reactions of 2, 3-dibromo-1H-inden-1-one afforded a wide range of arylated 1H-inden-1-ones. Sonogashira cross-coupling reactions gave alkynylated indenones. The reactions proceeded with very good regioselectivity in the less sterically hindered and more electron-deficient position 3.