1H NMR chemical shift calculations as a probe of supramolecular host–guest geometry

JS Mugridge, RG Bergman…

文献索引：Mugridge, Jeffrey S.; Bergman, Robert G.; Raymond, Kenneth N. Journal of the American Chemical Society, 2011 , vol. 133, # 29 p. 11205 - 11212

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被引用次数: 17

摘要

The self-assembled supramolecular host [Ga4L6] 12-(1; L= 1, 5-bis [2, 3- dihydroxybenzamido] naphthalene) can encapsulate cationic guest molecules within its hydrophobic cavity and catalyze the chemical transformations of bound guests. The cavity of host 1 is lined with aromatic naphthalene groups, which create a magnetically shielded interior environment, resulting in upfield shifted (1–3 ppm) NMR resonances for ...