Inorganic chemistry

Aerobic and Hydrolytic Decomposition of Pseudotetrahedral Nickel Phenolate Complexes

T Deb, GT Rohde, VG Young Jr, MP Jensen

文献索引：Deb, Tapash; Rohde, Gregory T.; Young, Victor G.; Jensen, Michael P. Inorganic Chemistry, 2012 , vol. 51, # 13 p. 7257 - 7270

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被引用次数: 16

摘要

Pseudotetrahedral nickel (II) phenolate complexes TpR, MeNi-OAr (R= Me, Ph) decompose on exposure to O2 and/or H2O. Aerobic decomposition yields organic products consistent with formation of phenoxyl radical, and concurrent reduction of O2 leads to oxidative modifications of the aromatic ring on the phenolate (R= Me) or the supporting ligand (R= Ph; see illustration). Hydrolysis yields free phenol and [TpMe, MeNi (OH)] 2 or [(TpPh, Me) 2Ni ...