Tetrahedron

Studies on aryl H-phosphonates. 3. Mechanistic investigations related to the disproportionation of diphenyl H-phosphonate under anhydrous basic conditions

A Kers, I Kers, J Stawiński, M Sobkowski, A Kraszewski

文献索引：Kers, Annika; Kers, Inger; Stawinski, Jacek; Sobkowski, Michal; Kraszewski, Adam Tetrahedron, 1996 , vol. 52, # 29 p. 9931 - 9944

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被引用次数: 37

摘要

Diphenyl H-phosphonate undergoes under anhydrous reaction conditions a base-promoted disproportionation to triphenyl phosphite and phenyl H-phosphonate. On the basis of 31P NMR data the most likely mechanism for this transformation was proposed. In order to substantiate these findings and to get a deeper insight into the chemistry of aryl H- phosphonate esters, we carried out also some studies on activation of phenyl and ...