Functionalized bis (pentafluoroethyl) phosphanes: improved syntheses and molecular structures in the gas phase

AV Zakharov, YV Vishnevskiy, N Allefeld…

文献索引：Zakharov, Alexander V.; Vishnevskiy, Yury V.; Allefeld, Nadine; Bader, Julia; Kurscheid, Boris; Steinhauer, Simon; Hoge, Berthold; Neumann, Beate; Stammler, Hans-Georg; Berger, Raphael J. F.; Mitzel, Norbert W. European Journal of Inorganic Chemistry, 2013 , # 19 p. 3392 - 3404

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被引用次数: 7

摘要

Abstract (C 2 F 5) 2 PNEt 2 represents an excellent starting material for the selective synthesis of bis (pentafluoroethyl) phosphane derivatives. The moderately air-sensitive aminophosphane is accessible on a multi-gram scale by treating Cl 2 PNEt 2 with C 2 F 5 Li. Treatment with gaseous HCl or HBr yielded the corresponding phosphane halides (C 2 F 5) 2 PCl and the so far unknown (C 2 F 5) 2 PBr in good yields. The hitherto unknown (C 2 F ...