Chemical Communications

A remarkable solvent effect toward the Pd/C-catalyzed cleavage of silyl ethers

H Sajiki, T Ikawa, K Hattori, K Hirota

文献索引：Sajiki, Hironao; Ikawa, Takashi; Hattori, Kazuyuki; Hirota, Kosaku Chemical Communications, 2003 , # 5 p. 654 - 655

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被引用次数: 24

摘要

The protection of alcohols as their silyl ethers has been recognized as a most useful protective method. Since the introduction of the tert-butyldimethylsilyl (TBDMS) protective group in 1972, 1 alcohols and phenols have been quite commonly protected as their TBDMS ethers. 2 TBDMS ethers have the virtue of being very stable to a variety of organic reactions. 2 In general, TBDMS ethers have been believed to be also stable under hydrogenation ...