Synthesis

A Facile Synthesis of Two Series of Multifunctional Carbon Compounds from α, α-Dihalo Ketones Using Allylsamarium Bromide

X Liu, S Zhang, J Di

文献索引：Liu, Xiaodan; Zhang, Songlin; Di, Jucai Synthesis, 2009 , # 16 p. 2749 - 2755

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摘要

Abstract The use of allylsamarium bromide to effect two different reactions on the common starting material, α, α-dihalo ketones, is presented. With DMF, α-halo-α-allyl aldehydes were obtained, while α-hydroxy-α-allyl aldehyde acetals were obtained in the presence of NaOMe/MeOH.