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Studies on furan derivatives. XII. Nucleophilic substitution of methyl 5??nitro??2??furancarboxylate. Preparation of methyl 5??phenoxy??2??furancarboxylates

A Tanaka, T Usui, M Shimadzu

文献索引:Tanaka, Akira; Usui, Toshinao; Shimadzu, Masaji Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 1241 - 1244

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被引用次数: 7

摘要

Abstract Twenty one methyl 5-phenoxy-2-furancarboxylates prepared from the reaction of methyl 5-nitro-2-furan-carboxylate with phenoxides via displacement of the nitro group. In the reaction of potassium 2-nitrophen-oxide with methyl 5-nitro-2-furancarboxylate at 110- 120, 2, 2′-dinitrodiphenyl ether was obtained as a main product.