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Silver??Catalyzed Incorporation of Carbon Dioxide into Propargylic Alcohols

W Yamada, Y Sugawara, HM Cheng…

文献索引:Yamada, Wataru; Sugawara, Yudai; Hau, Man Cheng; Ikeno, Taketo; Yamada, Tohru European Journal of Organic Chemistry, 2007 , # 16 p. 2604 - 2607

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被引用次数: 62

摘要

Abstract The combined use of a catalytic amount of silver acetate and a stoichiometric amount of DBU efficiently catalyzed the incorporation of CO 2 under mild reaction conditions into a wide range of propargylic alcohols bearing a terminal or an internal triple bond to afford the corresponding cyclic carbonates in high-to-excellent yields. All the cyclic carbonates obtained from the reaction were found to be single isomers. The geometries ...